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Nuclear Energy - The Theory


Nuclear Reactions

In the chemical reactions associated with combustion, the atoms in the molecules of the active materials rearrange themselves into new, more stable, molecules in which they are more tightly bound and in the process, releasing surplus energy in the form of heat.

In nuclear reactions it is the sub-atomic particles in the atomic nucleus, the protons and neutrons, which rearrange themselves to form new elements or isotopes with more stable nuclei. In this case the energy released by the reaction in the form of kinetic energy (manifest as heat) and electromagnetic energy (gamma radiation) is millions of times greater. See Energy Content


Note: The reactions discussed on this page are all nuclear reactions not chemical reactions.


Practical applications of the use of nuclear energy to generate electricity are given on the Nuclear Energy - The Practice page


Atomic Structure


Atomic Structure and Energy Levels

Definitions

The diagram above shows a representation of the constituents of an atom using Lithium as an example.


  • Notation
    • Atomic Number Z - is the number of protons in the nucleus
    • The Lithium atom has three electrons occupying 2 energy levels and three protons giving it an atomic number Z = 3 .

    • Atomic Mass A - is the number of nucleons in the nucleus.
    • The nucleus also includes four neutrons making up its seven nucleons and thus a mass number A = 7

    • Atomic Structure
    • The structure may be indicated by appending the mass number A after the name of the element or by indicating it as a superscript preceding the chemical symbol. Thus Lithium-7 or 7Li.

      The symbol may also indicate the full atomic structure ALiZ) by adding a subscript representing the atomic number Z preferably before, but alternatively after, the chemical symbol (depending on the capability of your word processor). Thus  7Li3


    An isotope of Uranium with 143 neutrons is called Uranium-235 and may be represented as  235U or 235U92 or U-235 


  • Nucleus - the very small dense region at the centre of an atom consisting of protons and neutrons. It contains nearly all the mass of the atom.
  • Nucleon - the common name for the protons and the neutrons which make up the nucleus of an atom. The mass number A is the number of nucleons in the nucleus.
  • Nuclide - a specific type of nucleus associated with a particular atom, characterised by its nuclear properties, such as the number of neutrons and protons and the energy state of its nucleus which differentiates it from the nuclei of other atoms.
  • Isotopes - elements or atoms which have two or more nuclides with the same number of protons but a different number of neutrons. They are distinguished by their mass number. That is the total number of protons and neutrons in the nucleus.
  • Since different isotopes of an element all have the same number of protons and electrons, they have the same or similar chemical properties, but they differ in mass due to the different numbers of neutrons in the nucleus and because of this the nucleus may be unstable. Too many or too few neutrons may make the nucleus liable to decay.

  • Electron (e-) - a fundamental subatomic particle which carries a negative electric charge.

    It has a mass of 9.1 X 10-31 Kg, and an electric charge of 1.602 X 10-19 Coulombs (denoted as -e)

    The electron gives rise to the electromagnetic properties of the atom as well as the chemical bonding with the nuclei of adjacent atoms. It can be bound to the atom or it can lead an independent life outside.
  • Energy Levels - Electrons can only contain distinct quanta of energy. This is often represented graphically as having distinct energy levels or electron orbits.
  • Spin - Is the intrinsic angular momentum about their own axis of subatomic particles, such as electrons. Electrons also possess orbital angular momentum about the nucleus of the atom. See also Pauli and Spin
  • Positron (e+) - the antiparticle of the electron with same mass and spin but with a positive charge equal in magnitude to that of the electron's negative charge. Every particle has a corresponding antiparticle. See also Dirac and the Positron.
  • Proton (p) - a subatomic particle with a positive electric charge of equal magnitude, but opposite sign, to the charge on the electron. It is much larger than the electron and has a mass of 1.6726 X 10-27 Kg about 1836 times the electron's mass. Together with the neutrons, the protons form the nucleus of the atom. The number of protons in the nucleus is called the atomic number Z and this determines the atom's chemical properties.
  • Neutron (n) - a subatomic particle with no net electric charge. It has a mass of 1.6749 X 10-27 Kg, slightly more than a proton. Free neutrons are not found in nature. They would decay into protons and electrons.
    • Fast Neutron - A high energy neutron moving at around 20,000 Km/s with very high energy of more than 1 Mev. Neutrons produced by fission reactions are known as "fast" neutrons. Neutrons released immediately in a nuclear fission event are also called "prompt neutrons".
    • Thermal Neutron - A "slow", low energy neutron moving at about 2.2 km/s with energy less than 1 eV. Slow neutrons may be emitted by non-fission nuclear reactions such as nuclear decay or may be fast neutrons which have been slowed down after a set of collisions with atomic nuclei. Neutrons which are emitted by the radioactive decay of some of the fission fragments are also called "delayed neutrons".
  • Nuclear Cross Section (sigma σ) - The the probability that a nuclear reaction can occur. It is a measure of the notional cross sectional area that a target nucleus effectively presents to an impinging particle which results in a given reaction. Its standard unit of measurement is the "barn" where 1 bn = 10-28 m2. There are several possible reactions: principally fissioning (and possubly fusion), capturing (absorption possibly resulting in decay or transmutation of the element) and scattering.
    • Isotopes that fission, are fissionable fuels and have a corresponding fission cross section which is a measure of the relative fissility of the isotope.
    • Nuclides that tend to absorb a neutron and either decay or retain the neutron in its nucleus are called neutron absorbers and will have a capture cross section for that reaction.
    • The remaining isotopes will simply scatter the neutron, and have a scatter cross section.

    Note that the magnitude of the cross section depends on the energy level of the impinging particle.

    Paradoxically, the target nucleus will appear to be significantly larger to a slower bombarding particle than to a faster, high energy one due to the greater probability that the slower particle will be absorbed by the nucleus rather than deflected. This is because the longer an impinging neutron stays in the neighbourhood of a target nucleus, the greater the chance that the nucleus will capture it.

  • The "barn" was named by H.G. Holloway and C.P. Baker at Purdue University in 1942. It is said that the name was derived from a target sufficiently large that even a novice war-time rifleman could not miss it.

  • Neutrino (nu ν) - very small subatomic, elementary particles without an electric charge which are produced by the decay of radioactive elements. Neutrinos and anti neutrinos are affected only by the weak nuclear force. Like the neutron, having no charge, they are not affected by electromagnetic forces. See also Pauli's Neutrino
  • Antineutrino (-ν) - the antiparticles of neutrinos emitted during beta decay in which a neutron decays into a proton, electron, and antineutrino.
  • Coulomb Forces - the electrostatic forces between charged particles. Oppositely charged particles attract eachother and similarly charged particles repel eachother. The Coulomb force is the force which binds negatively charged electrons to the positively charged nuclei of atoms. The variation of the force with the distance between particles obeys the inverse square law.
  • The Strong Nuclear Force - one of nature's four fundamental forces. It is an attractive force which holds together the nucleons (neutrons as well as protons) in the nucleus of an atom against the repulsive Coulomb forces due to all the positive charges on the protons which would otherwise cause the nucleus to fly apart. The magnitude of the strong nuclear force is much greater than the electrical Coulomb force binding the electrons to the nucleus but it is only effective over a very short range of about 10-15 metres. Though no law governing the action of the strong force between particles has been formulated, some theorists have suggested that, as an approximation, the magnitude varies inversely as the seventh power of the distance between the particles since this is consistent with its very restricted effective range.
  • The Weak Nuclear Force - another of nature's fundamental forces, (the others are electromagnetism and gravitation). It governs the radioactive decay of unstable subatomic particles and nuclear fission. The weak reaction is a form of radioactivity which can transform a neutron into proton and a proton into neutron, resulting in transmutation of the elements, with the following two reactions:
    • Electron Decay - A neutron is transformed into a proton by losing a negatively charged electron (beta particle) and an antineutrino and is left with a positive charge.
    • n ⇒ p + e- + -ν

      See also Pauli and Beta Decay.

      Electron or beta decay is the basis of radiocarbon dating when the radiocarbon isotope of Carbon is transmuted into Nitrogen by beta decay. See explanation of radiocarbon dating.

    • Positron Decay - A proton is transformed into a neutron by losing a positively charged positron and a neutrino leaving it with no charge.
    • p ⇒ n + e+ + ν

      It is positron decay which initiates the Sun's nuclear fusion. A Hydrogen atom (proton) is transformed into a neutron which then fuses with another Hydrogen atom under the Sun's conditions of extreme temperature and pressure to form Deuterium an isotope of Hydrogen. The Deuterium nuclei undergo further fusion reactions to produce Helium with the release of huge amounts of energy. See more about Deuterium Fusion Fuels below.

    The effectiveness of the weak force is confined to a distance range of 10-17 metres, about 1 percent of the diameter of a typical atomic nucleus.

  • Binding Energy is derived from the strong nuclear force. It is defined as the energy that is released when a nucleus is assembled from its constituent nucleons and is thus a measure of the amount of energy held within the bonds of the atom and corresponds to the energy required to be put in again to pull the nucleus apart. The mass of the nucleus of an atom is less than the sum of its constituent protons and neutrons (the nucleons) and the difference represents the mass equivalent of the binding energy given by Einstein's mass-energy equivalence formula
    Eb=ΔMc2

    Where Eb is the binding energy and ΔM is the mass difference.

  • The larger the nucleus, the greater the internal repulsive forces due to the greater number of protons and less energy must be applied to remove a nucleon from the nucleus, hence the binding energy is lower. The greater the binding energy, the more stable the atom is. The following graph shows the binding energy of nucleons of different elements. The total binding energy of the nucleus is given by multiplying the nucleon binding energy by the number of nucleons in the nucleus (The atomic mass A).


    Nuclear Binding Energy


    When there is an increase in the total binding energy of a system, the system has become more stable by releasing an amount of energy equal to the increase in the total binding energy of the system. Therefore, the energy liberated in the fission or fusion processes is equal to the increase in the total binding energy of the system.

  • Mass Defect - Mass Deficiency This is the difference between the mass of a nuclide and the sum of the masses of its individual nucleons. Both of these factors can be measured by mass spectrography and in practice, this provides a way of determining the binding energy. Once this mass difference, is known, the binding energy of any nucleus can be calculated from Einstein's formula E = mc². The mass defect of a nucleus is thus the mass equivalent of the energy released by the fusion of its constituent nucleons.
  • Transuranium Elements - are the chemical elements with atomic numbers greater than 92, which is the atomic number of Uranium. All of these elements are unstable and decay radioactively into other elements.

See also Aston's discovery of binding energy.


Decay, Fission, Fusion and Capture

When a neutron impinges on an atomic nucleus, several different types of nuclear reactions are possible: decay, fission and fusion, capturing of the neutron, plus a simple scattering of the impinging particles without a nuclear reaction.

  • Nuclear decay occurs when small bits of the atomic nucleus are ejected from an unstable atom transforming it into a different, more stable species. Decay resulting from ejection of Helium atoms (alpha particles) is known as alpha decay, while decay resulting from the ejection of electrons (beta particles) is known as beta decay.
  • The timescales for the decay of unstable isotopes range from fractions of a second to billions of years. See examples below.

  • Fission is the splitting of an atom to form two complete smaller atoms.
  • When a large unstable nuclide splits into two smaller stable nuclides, the combined binding energy holding each of the smaller nuclides together is less than the energy needed to hold the larger nuclide together and the surplus energy is released.

    • In nuclear applications fission is normally induced by bombarding the atom with neutrons.
    • Spontaneous fission may also occur, albeit at a much reduced rate. This is a natural and completely uncontrollable process in which a nucleus splits randomly of its own accord, without being hit by a neutron. This fission typically leberates two to three neutrons which can go on to cause further induced fissions.
  • Fusion is the fusing of two smaller atoms to form a larger atom.
  • In the case of fusion, the binding energy of the new, larger stable nuclide is less than the combined binding energy of the individual nuclides which formed it and so the surplus is energy released.

    In all three of the above transformations, decay, splitting and fusing, the nuclear reaction is accompanied by a tiny reduction in the total mass of the components and the corresponding release of energy.

  • Neutron Capture is the the absorption by an atomic nucleus of one or more neutrons colliding with it and merging into a heavier nucleus. The new nucleus may form a stable isotope of the original element or it may be unstable, decaying into a more stable element by the emission of alpha or beta particles.
  • Transmutation - the changing of one element into another by radioactive decay, nuclear bombardment, or similar processes.

The fission reaction can proceed uncontrollably and needs to be slowed down whereas the fusion reaction takes prodigious mounts of energy to speed it up and get it started. The fusion process is therefore inherently stable with no threat of runaway.


A word about Iron (56Fe26)

Iron is believed to be the tenth most abundant element in the universe and the fourth most abundant in the Earth's crust.

The graph of binding energies above shows that the Iron atom, situated in the middle of the periodic table, has the highest binding energy and hence is the most stable element. It neither splits nor fuses with other atoms in a nuclear reaction. It represents the dividing line between fission and fusion.

The closer an element's mass number is to that of Iron the more stable it is and the less the likelihood that it will split or fuse with other atoms easily. The further an element is from Iron in the periodic table the less the binding energy holding it together, so that the elements at the extremes of the periodic table are the least stable and the most reactive. The large heavy atoms at the top of the table can achieve more stable equilibria by fission and the small light atoms at the lower end of the table can reach more stable states by fusion.

Attempting to fuse two atoms which are heavier than iron or to split an atom which is lighter than iron will require energy to be expended and will result in daughter elements, with less stable atoms having less binding energy, further way from the maximum stability point.


In summary - Nuclear fission in an element heavier than Iron produces energy and fission in any element lighter than Iron requires energy. By contrast, nuclear fusion reactions between elements lighter than Iron produces energy and fusion in elements heavier than Iron requires energy.


Nuclear Decay

Nuclear or radioactive decay was first discovered in some naturally occurring minerals containing elements such as Uranium and Radium. It is the spontaneous process which occurs in radioactive materials by which the nuclei of unstable atoms, the parent nuclides, gradually break up and are transformed into more stable isotopes or into atoms of a different type, the daughter nuclides, consequently losing energy by emitting radiation in the form of ionised particles and / or electromagnetic waves.

Example

The most common isotope of Uranium, U-238 decays by alpha decay to form Thorium-234, a radioactive silvery metal, with the emission of one Helium atom (alpha particle). Thus

238U92    ⇒    234Th90    +    4He2

The daughter nuclide (thorium-234) has 2 fewer protons and neutrons than the parent nuclide (uranium-238)


At the atomic level, nuclear decay is a random process so that it is impossible to predict when a particular atom will decay. However in practical samples which contain a large number of similar atoms, the average decay rate is predictable.


  • Radiation and Energy Release
  • The nature of the decay and the energy released depend on the specific elements involved and the type of radiation emitted by the decay. Nuclear decay may be accompanied by up to three types of ionising radiation plus non-ionising neutron radiation.

    • Alpha (α) radiation
    • Alpha particles are Helium - 4 nuclei (2 protons and 2 neutrons). They are large, heavy particles with relatively low energy and are readily stopped by a sheet of paper.

      Typically an alpha decay of a single Uranium-238 atom releases 4.3MeV (6.9 X10-13 J) of energy. (but the rate is random and not controlled)

    • Beta (β) radiation
    • Beta particles are electrons. They have high energy but can be stopped by a thin sheet of aluminium.

      The energy released in a typical β-decay compared with alpha emission is very low, with the energy of a single electron being in the order of 1eV (1.6 X 10-19 J). Most of this energy is in the form of the kinetic energy of the emitted electron.

      Beta decay occurs when there are "too many" neutrons in a nucleus, with the result that a neutron converts into a proton — with the emission of an electron. The conversion of the neutron into a proton increases the atomic number by one (one more proton in the nucleus) while leaving the mass number unchanged (the total number of protons and neutrons is unchanged). Thus the effect of beta decay is to increase the atomic number by one, thereby creating an element one position further up in the periodic table.

    • Gamma( γ) radiation
    • Gamma radiation is high frequency electromagnetic radiation (waves), consisting of high energy photons (not particles). Similar to X rays, but carrying much more energy, gamma rays have high penetrating power but can be absorbed by thick lead shielding or several feet of concrete. (X rays come from the electron shells whereas gamma rays come from the nucleus).

      Gamma decay may be spontaneous or induced. This is because atoms can absorb photons and re-emit them at many different energies. The consequence is that the energy released by a single gamma radiation event may be in the range from 10,000eV to 10MeV.

    • Neutron Radiation
    • Neutron rays consist of free particles of high energy neutrons which are considered to be non-ionising radiation since neutrons carry no charge. They are not usually the result of decay but of nuclear fission or possibly fusion during which neutrons may be ejected. (See below). Spontaneous neutron emission (decay) can occasionally occur however with some isotopes of atoms containing excess neutrons and some very heavy atoms in which a neutron is simply ejected from the nucleus.

      Neutron radiation is best absorbed by materials containing hydrogen such as water or plastic. Shielding against neutron radiation may be provided by 0.5 m to 2 m of water depending on the neutron energy.

      The initial energy of a neutron is about 1 MeV (1.6 X 10-13 J)


  • Decay Energy
  • The break up of a single atom with the release of energy is called a decay event. The amount of energy released in each event is equal to the difference in the binding energy of the atom before the reaction and the sum of the binding energies of the decay products resulting from the reaction. This amount is very small, and is measured in electronVolts (eV) (or Millions of electronVolts MeV)

    For a material sample, the number of events occurring is proportional to the number of atoms present, in other words the mass of the sample. For practical samples, it is more convenient measure the rate of energy release rather the absolute amount of energy released, in other words, the power, measured in Watts.


    Decay Rate and Isotope Lifetime

    The unit of radioactive decay or the frequency of nuclear events, is known as the Becquerel (Bq) which is defined as one transformation (or decay event) per second.

    Since radioactive decay results in the emission of ionised particles, a simple way of measuring the number of events is by counting the number of particles (ions) as they are released using devices like Geiger counters.


    • Nuclear Decay Rate
    • The rate of nuclear decay or energy released is thus proportional to the amount of radioactive material remaining in the sample and the frequency of the nuclear events. This is the classic exponential decay represented by the equation:

      Nt = N0e-λt

      where

      N0 is the initial quantity of radioactive (decaying) nuclides measured by mass or numbers of atoms

      Nt is the number of nuclides remaining ( not yet decayed) after time t

      λ is the decay constant (a measure of the rate at which the nuclide releases radioactive emissions)

      e is the natural exponential = 2.718.

      Note that nuclear disintegrations are randomly occurring events and the value of λ is a statistical probability.


      The rate of radioactive emissions of a radioactive sample is directly proportional to the amount of radioactive nuclides present in the sample. Thus:

      A=λNt

      so that

      A=λN0e-λt

      where A is the activity or frequency of nuclear events or disintegrations per second in Becquerels


      The mean, or average lifetime of a nuclide, (Τ) also called the time constant, is the sum of the lifetimes of all the individual nuclides in a sample, divided by the total number of nuclides present. It is the reciprocal of the decay constant. Thus:

      Mean Life Τ=1/λ

       

    • Half Life
    • The rate of decay of a radioactive nuclide is usually quoted as its half-life.

      The half-life () is the time when the expected number of nuclides that have decayed is equal to half of the original number. (That is the time when when Nt = N0/2)

      Substituting in the decay equation (Nt = N0e-λt)

      2 = e

      Rearranging, the half life is given by:

      = Ln (2) /λ = 0.693

      where Ln (2) is the natural logarithm of 2 = 0.693


      Examples 1: Half life

      Different materials have different rates of decay and are characterised by their half lives.

      The half life of Uranium-238 is 4.5 billion years, roughly the age of the earth. The rarer Uranium-235 (0.72% of all Uranium) has a half life of 704 million years and Plutonium-239 which is virtually non existent in nature has a half life of 24 thousand years. Radium which is found in very small quantities in Uranium ores has thirteen isotopes, the most common of which is Radium-226 which has a half life of 1622 years.

      The shorter the half life of a radioactive element, the less of it will remain in the earth's crust.

      Cobalt-60 used in medical applications is not found in nature due to its short half life of 5.27 years. It is produced artificially by neutron activation of Cobalt-59.

      The half life of the Carbon isotope 14C6 decaying to Nitrogen 14N7, which is used for radiocarbon dating, is 5,730 years.

      The beta decay of the Nitrogen isotope 16N7 transforms the Nitrogen atom into an Oxygen 16O8 atom within a few seconds of the Nitrogen isotope being created.


    • Activity Rate
    • The activity rate in Becquerels per gram is given by

      A/M=λNt / M = N0*ln(2)/, x M

      where

      M is the molar mass of the atom (Assuming the initial quantity of radioactive material = 1 mole)

      N0 is the number of atoms per mole (Avogadro's number).

      is the half life of the atom in seconds (1 year = 31.536 x 106 seconds)


      Example 2 - Cobalt-60 Activity rate

      The molar mass M of the Cobalt-60 nuclide is is 59.93 grams

      The half life is 5.27 years

      Thus the activity rate per gram is

      A/M = 6.022 x 1023 x 0.693/ (5.27 x 31.536 x 106) x 59.93 = 41.9 x 1012 Bq/g (or 41.9 TBq/g)


    • Radiated Power
    • The radiated power associated with each decay event is given by

      W = Δm * A/M

      or W = E * A/M

      Where:

      W is the radiated power

      Δm is the mass defect due to the disintegration of the isotope

      E is the binding energy released (equivalent to the mass defect)


      Example 3 - Cobalt-60 Radiated Power

      Cobalt-60 decays into Ni60.

      The mass difference, Δm is 0.00303 amu (atomic mass units).

      The corresponding radiated energy E is 2.8 MeV or 4.48 x 10-13 Joules (or Watt seconds)

      From the radiated power equation the radiated power per gram of Cobalt-60 is given by:


      W = E x A/M = 4.48 x 10-13 X 41.9 x 1012 = 18.77 W/g


    Nuclear batteries use the heat evolved from nuclear decay.

     

Nuclear Fission

When an atomic nucleus is struck by a neutron, three principal reactions are possible. The nucleus might fission, it might capture the neutron without fissioning, or it might simply deflect or scatter the neutron. Each process has a probability of occurring and these probabilities depend on the speed or energy of the incoming neutrons. The probability of fission is defined by the nuclear cross section (See above)

 

Nuclear fission occurs when a neutron collides with a nucleus of a large atom such as Uranium and is absorbed into it causing the nucleus to become unstable and thus split into two smaller more stable atoms with the release of more neutrons and a considerable amount of energy. Nuclear fission can also occur naturally with the spontaneous decay of radioactive material or it can be initiated by bombarding the fuel consisting of fissionable atoms with neutrons. Neutrons, which are electrically neutral, can penetrate relatively unhampered into the atomic nucleus and are used as the bullets to initiate the fission rather than protons because, with a positive charge, the protons would be strongly repelled by the positively charged nucleus. See Coulomb Barrier below.


  • Fissile Material
  • Fissile materials are those fissionable materials which are capable of sustaining a chain reaction when struck by neutrons with low kinetic energy (slow or thermal neutrons). When they absorb a thermal neutron, the binding energy released is much greater than the critical energy required for fission and so they are said to be fissile.

    See also Neutron Energy

    The three most important fissile materials which can be obtained in large enough useful quantities are Uranium-233 and Uranium-235, both dense soft silvery metals and Plutonium-239, also a dense silvery white metal.


  • Fertile Material
  • Fertile materials are isotopes which are capable of becoming fissile by capturing fast moving neutrons possibly followed by radioactive decay. Examples are Uranium-238, Plutonium-240 and Thorium-232.


  • Fissionable Material
  • Fissionable materials are those whose atoms can undergo induced nuclear fission when struck by a free neutron. Fertile materials need a fast moving neutron to initiate fission while fissile materials need a slow moving neutron for fission.

    Fissionable materials are not necessarily fissile. Thus, although Uranium-238 is fissionable, it is fertile but not fissile.


  • Fission Energy Release
  • Several isotopes of uranium can undergo induced fission. But the only naturally occurring isotope in which fission can be induced with thermal neutrons is Uranium-235 which splits into Barium-141, a soft silvery metal, and Krypton-92, an inert gas, and surplus free neutrons averaging about 2.4 neutrons per event. The following diagram shows the process in more detail.


Nuclear Fission Chain Reaction


The process can be represented by the following equation:


235U92    +   1 n0   ⇒    140Ba56    +    96Kr36    +    3 1 n0    +    @ 200MeV

 

The energy released by fission of one atom of Uranium-235 is 200 MeV


The energy released at the atomic level can be calculated from the binding energies of the parent and daughter atoms as shown in the following table:


Corner

Binding Energy Change with Fission

Corner

Atom

Number of Nucleons

Binding Energy

Per Nucleon (MeV)

Total Binding Energy per Nuclide (MeV)

Combined Binding Energy (MeV)

Fission Energy Release (MeV)

Uranium-235

235

7.6

1786

1786

166.3

Barium-141

141

8.3

1170.3

1952.3

Krypton-92

92

8.5

782

Other Fission Products (Particles and Radiation)

33.7


The Uranium-235 nuclide has a binding energy of about 1786 MeV. The total binding energy of the nuclides of Barium and Krypton which remain after fission amount to about 1952 MeV. The difference of 166 MeV corresponds to the energy released in the fission process. In addition there will also be several small energy releases totaling about 33 MeV associated with ejection of the neutrons and other particles as well as beta and gamma radiation.

Thus the total energy released by the fission of 1 atom of Uranium-235 is about 200 MeV which corresponds to 3.2 X 10-11 Joules.


The energy released from practical amounts of fuel can be calculated as follows:


1 Atom of Uranium-235 weighs 235 amu (atomic mass units) = 3.92 X 10-25 Kg

Therefore 1 kilogram of Uranium 235 contains 1/235 amu atoms = 2.54 X 1024 atoms

The energy released from 1 kilogram of pure Uranium-235 is therefore (3.2 X 10-11) X (2.54 X 1024) = 8.1 X 1013 Joules.

Ignoring the conversion efficiency loss, which may be 50% or more, the theoretical energy released of 8.1 X 1013 Joules is equivalent to 22.5 GWh of electrical energy or the explosive power of 21,400 (short) tons of TNT.

See conversion factors


The mass consumed in the transformation is given by Einstein's formula E=mc2

From one atom of Uranium-235 the mass of Uranium actually converted into the 200 MeV of energy is 3.56 X 10 -28 Kg, an almost infinitesimal amount.

From the one kilogram of Uranium-235 fuel consumed, the mass of Uranium actually converted into energy is (3.56 X 10 -28) X ( 2.54 X 1024) = 9.04 X 10 -4 Kg = 0.9 grams


By comparison, the fission of one atom of uranium produces 10 million times the energy produced by the combustion of one atom of carbon from coal.

Just 0.6 grams of Uranium-235 were consumed by the atomic bomb which devastated Hiroshima in 1945.


  • Chain Reactions
  • As noted above, nuclear fission is initiated by bombarding the nuclei of large unstable atoms with neutrons which cause nuclei to split releasing more neutrons. These neutrons released by the fission process can go on to split further atoms thus releasing even more neutrons. If the number of fissile atoms is small, as in a low mass sample, or if they are widely dispersed, as in an impure sample, most of the neutrons released by the initial fission will not encounter more fissile atoms. They will lose their energy by collision with other atoms and molecules and the reaction will die out. If however there is a large mass of more concentrated fuel, a larger number of neutrons will impinge on more fissile atoms triggering yet more fissions in a chain of events creating more neutrons as each neutron is absorbed. The reaction thus becomes self sustaining and the mass of the sample or the fuel load at which the chain reaction just becomes possible is called the critical mass.

    Note that depending on the target material, fission may be initiated by either "fast neutrons" or "slow neutrons". The neutrons emitted by nuclear fission are however always fast (prompt) neutrons.

    Nuclear power applications, based on the controlled fission of Uranium-235, typically use slow neutrons to create and sustain the fission so that the fast neutrons emitted by the fission must be moderated (slowed down) before they can create the next fission.

    On the other hand, nuclear weapons which depend on very fast uncontrolled reactions, use these fast neutrons directly. They can not however use slow neutrons, even with Uranium-235 fuel. This is because the slower reaction time between fissions would be not much greater than a chemical reaction, so that the fuel would heat up, melt and disperse causing the chain reaction to shut down prematurely with a fizzle, or worse still, causing the the fissile core to rip itself apart. Furthermore, because slow neutrons require a moderator to slow down the fast neutrons liberated by the fission, this would increase dramatically the mass of the bomb making it too heavy to be viable.

    The effective neutron multiplication factor K is defined as the ratio of the number of neutrons produced by fission in one generation to the number in the preceding generation. It refers to the conditions of the population of neutrons within the reactor core. This is not the same as the average number of neutrons created by the fission reaction (2.4 in the case of Uranium-235) since some neutrons are absorbed in non-fission reactions and others escape from the system without being absorbed. The way in which a fission chain reaction proceeds depends on the value of K.

    • Sub-criticality (K < 1): The system can not sustain a chain reaction. A reaction may be started by external neutrons but it dies out fairly rapidly.
    • Criticality (K = 1): Every fission cause on average one more and the reaction continues at steady rate. This is is known as the critcal state and is the operating state of a power reactor.
    • Super-criticality (K > 1): With a very high concentration of fissile material, each fission causes K more fissions and the number of neutrons escalates exponentially in an uncontrollable chain reaction with a possible explosive release of energy.
    • Prompt Critical If criticality (K ≥ 1) is achieved with fast neutrons alone without including any delayed neutrons, it is said to be prompt critical. This is a run-away condition that usually is unstoppable

    In a nuclear reactor, once a critical mass of fuel has been assembled in the reactor core, the population and energy of the neutrons must be controlled to prevent the possibility of a runaway action with disastrous consequences, while at the same time maintaining the chain reaction. This is the function of the control rods whose purpose is to remove neutrons from the reactor core.


  • Critical Mass
  • In practical terms the effective critical mass (when K=1) of a given fissile material used in a nuclear reactor depends on many other attributes, such as the fissility (fission cross section) of the fuel, its the degree of enrichment (purity), its shape, temperature, density, and whether it is contained within a neutron-reflective substance. Thus the amount of fissile material needed to start a nuclear reaction varies with the conditions under which it is being considered. The mass of material defines criticality, but only if the conditions under which it is being used are specified. This means that under different conditions, any given form of fissile material will have different critical masses.

     

    The lowest critical mass of an unmodified sample of enriched Uranium-235 is 52 Kg in a bare sphere 17 cm (6.7 inches) in diameter. For Plutonium-239 the corresponding figures are 10 Kg in a sphere of 9.9 cm (3.9 inches) in diameter.

    In nuclear reactors which depend on fission of Uranium by slow neutrons, taking into account the degree of dilution of the desired isotope in the fuel bulk, the critical mass of Uranium-235, enriched to only 20%, will be as high as 400Kg rising exponentially as the enrichment is decreased further.

    The critical mass is different for nuclear weapons whose design depends on fission by fast neutrons and requires a much higher degree of enrichment.

     

    A nuclear critical condition achieved with prompt neutrons is called prompt critical.

     

    • Tampers
    • In nuclear weapons, the use of tampers, heavy metal jackets around the fuel, which reflect escaping neutrons back into the fuel mass can reduce the critical mass by a factor of two or three. These are constructed from the densest of metals which have a high scatter cross section. In this way, about 15 kg (33 pounds) of Uranium-235 or about 5 to 10 kg (11 to 22 pounds) of Plutonium-239 at normal density can be made critical reducing the mass of fissile material required for criticality.

      There is a secondary benefit from the tamper since its solid construction also prevents or at least retards the thermal expansion of the fuel mass as the fission progresses, which could otherwise cause the fuel mass to lose criticality due to its reduced density.

       

    • Compression
    • With some fuels, the critical mass can also be lowered by compressing the fissile core, because at higher densities, emitted neutrons are more likely to strike a fissionable nucleus before escaping. This is a possibility with Plutonium which has twenty basic allotropes which are forms of the same element in the same physical state (solid, liquid, or gas) but which differ from each other in their physical properties such as density and crystal structure amongst others. By means of high pressure and temperature, phase transitions can be induced in suitable light Plutonium allotropes reducing their volume, transforming them into higher density allotropes, with density increased from 16.00 g/cm3 to 19.86 g/cm3 thus reducing the effective critical mass of the fuel.

      As with the tamper, the high pressure compression method also retards the thermal expansion of the fuel mass as the fission progresses, thus reducing the possibility of the fuel mass losing criticality.

     

    Thus the term "critical mass" is not precisely defined for all circumstances and can be misleading so that in some cases "critical condition" may provide a more useful, though more complex, descriptor.


  • Other Nuclear Fission Reactions
  • The content of fissile Uranium-235 used in nuclear reactors is less than 1% in reactors using natural, unenriched fuel and up to 5% or 6% in reactors using enriched fuel. Almost all of the balance (94% to 99%) is non fissile Uranium-238 with a tiny amount (0.0055%) of Uranium-234. The free neutrons bouncing around inside a Uranium reactor don't just react with the Uranium-235, they can also react with other Uranium isotopes they encounter as well as any other elements present in the nuclear pile to produce other transmutations and disintegrations.

    • Plutonium
    • On a cosmic timescale, Plutonium has a relatively short half life of only 24,000 years which means that it does not occur naturally on earth. On a contemporary timescale however 24,000 years is an awful long time for Plutonium waste, produced by nuclear reactions, to remain radioactive.

      • Production
      • Since the bulk of the fuel charge in a conventional Uranium fuelled reactor is Uranium-238, the free neutrons released by the fission of Uranium-235 have a high probability of colliding with Uranium-238 atoms. The collision of both fast or slow neutrons with Uranium-238 can result in the capture of the neutron and the transformation of the Uranium-238 into Uranium-239, an unstable isotope which decays within a few hours to become Neptunium-239 with the emission of a beta particle (an electron). This unstable Neptunium isotope undergoes further beta decay losing another electron during the next several days to become the more stable Plutonium-239, one of fifteen isotopes of Plutonium, which has a half life of 24,000 years. See details of the Uranium-238 decay process.

      • Fission
      • Plutonium-239 however is fissile, more readily so than Uranium-235 emitting more excess neutrons per fission than Uranium-235 so that a chain reaction can be achieved with less than one third of the critical mass of fuel . Plutonium-239 can however also capture fast neutrons as well as slow neutrons causing even more fissions.

        A slow neutron can split Plutonium as follows into Barium and Strontium with the emission of 3 neutrons and energy of 207 MeV which is not much different from the energy released by the fission of Uranium-235


        239Pu94    +   1n0   ⇒    142Ba56    +    95Sr386    +    3 1n0    +    @ 207 MeV


The production of Plutonium-239, the fuel used in nuclear weapons, is thus inevitable in conventional Uranium fuelled nuclear reactors and Plutonium fissions provide about one-third of the total energy produced in a typical mature Uranium fuelled commercial nuclear power plant.


Power from Nuclear Fission

Nuclear power generation is now firmly established throughout the world and is based on controlled nuclear fission. See the page on Nuclear Fission - The Practice


Nuclear Fission Weapons

Fission weapons are examples of the uncontolled escalation of the number of nuclear fission reactions in a supercritical mass of a fissile element.

Uranium-235 is used here to illustrate the reactions involved. The more fissile Plutonium-239 undergoes similar reactions but the bomb design must be modified to take account of the faster fissile reactions.


  • Neutron Multipication
  • When the neutron multiplication factor K of the assembled fuel mass is greater than unity (K>1), the fuel mass is said to be supercritcal and the fission caused by each neutron collision will release more than one neutron. In the case of U-235, on average, each fission of a U-235 atom produces about 2.4 new neutrons. Some neutrons escape without adding to the chain reaction and some are absorbed by U-238 atoms and do not produce additional neutrons to add to the chain reaction. If only two of the released neutrons are absorbed by new U-235 atoms, the number of fissions will double each generation. Thus with each generation the number of released neutrons will increase as 1,2,4,8,16,32,64 and so on, increasing exponentially so that by the 10th generation there will be 1,024 fissions and by the 80th generation, about 6 x 10 23 fissions.

    (Footnote: The example of 80 generations was chosen, in this explanation, for convenience because the number 6 x 10 23 happens to be equal to Avogadro's Number which corresponds to the number of particles or atoms in 1 mole of a substance. The molar mass, in grams, of one mole of atoms is equal to the atomic number of the particle. Thus for U-235, the mass of the 80 generations of fissioned atoms will be 235 grams.)


  • Initiation
  • Detonation of the bomb occurs in two stages, first a conventional explosive charge is necessary to rapidly assemble the supercritical mass from the subcritical components, followed by the triggering of the chain reaction of the fissile material by a neutron source, known as an "initiator". This second stage introduces neutrons into the supercritical mass of the fuel and needs to occur at a precisely controlled instant once the supercritical mass has been assembled to avoid predetonation which could cause incomplete fission that could destroy the bomb before sustained fission was achieved.

    Although the bomb's chain reaction is sustained by fast neutrons, emitted by the fission reaction itself, such neutrons are not available before the fission has commenced so that the fission reaction can not practically be initiated by fast neutrons. This is also because fissile materials have a very low fission cross section with fast neutrons which means that the probability of fission is also very low. The initiation of the fission in a nuclear weapon therefore depends on the introduction of slow (thermal) neutrons into the fuel mass because the fissile fuel materials have a higher fission cross section with slow neutrons, and thus a much higher probability of fission, than with fast neutrons. Consequently it is necessary, and easier, to start the fission with slow neutrons. Once the fission has started however there is no further need for thermal neutrons since the fission itself quickly produces the enormous neutron flux of fast neutrons necessary to maintain the runaway nuclear chain reaction.


    The initiators, also known as "Urchins", used in the Manhattan Project depend on the use of alpha particles from radioactive Polonium-210, impinging on Beryllium-9 nuclei to produce Beryllium-8 with the liberation of free thermal neutrons necessary to start the fission of the fissile Uranium or Plutonium fuel. Polonium and Beryllium pellets were contained in two separate, small containers isolated from eachother by a foil, in a spherical capsule about the size of a golf ball located in the core of the bomb. After the detonation of the explosive charges, the initiator is crushed by the incoming projectile piece in the case of the gun type Uranium bomb, or by the shock wave of the implosion in the Plutonium bomb, mixing the Polonium and Beryllium. This releases the thermal neutrons to trigger the detonation of the critical mass of the fissile fuel and hence the atomic explosion.


  • Energy Release
  • As noted above, the fission of each atom of U-235 releases 200 Mev (3.2 X 10-11 Joules) of energy. This is 50 million times the energy of 4 eV (6.5 x 10-19 Jules) released by each atom of carbon burned in fossil fuels. After 80 generations, 235 grams or 6 x 10 23 atoms of U-235 will have fissioned and the total energy released will be 1.2 X 1026 Mev (1.9 X 1013Joules). This is equivalent to the energy released by the explosion of 5 kilotons of TNT. This example shows the mass consumed and the energy released in 80 fission generations initiated by just a single neutron in a supercritical mass of U-235 fuel.

    In an actual bomb, the critical mass will be several times the 235 grams used in the calculation here so that there will be many more fission generations. Furthermore the initial fissions are typically initiated by a neutrons from a separate generator which could set several chain reactions in motion simultaneously, thus increasing the potential output of energy from the fuel mass, though they reactions should occur within nanoseconds of eachother to be effective. Consequently the energy released in a practical bomb will be several times more than the 5 kilotons calculated in the example above.

    Because of the exponential progress of a chain reaction starting from a single neutron collision, there are relatively few fissions from the first few generations of the chain reaction and hence realtively low energy release during this early period. For the same reason, the the vast majority of the fissions occur during the last few generations of the reaction so that the majority of the energy release also occurs during this last short period.

    Because the reaction occurs with fast neutrons and is also uncontrolled, the energy is released with explosive force.


  • The Reaction Time
  • The time taken between each fission in the chain reaction is determined by the speed of the neutrons and also depends on the distance they travel before being captured by the next atomic nucleus. The average distance between the collisions is called the "mean free path" (λ). In fissile materials such as Uranium-235 at maximum normal densities the mean free path for fission is roughly 13 cm for 1 MeV neutrons (a typical energy for fission neutrons). These neutrons travel at 1.4 x 109 cm/sec, yielding an average time between fission generations of about 10-8 seconds (10 nanoseconds), a unit of time which in the jargon of the early experimenters was called a "shake".

    In summary, the total time to complete the 80 generations will be less than 1 microsecond during which 235 grams of the U-235 supercritical fuel mass will be fissioned releasing energy equivalent to the explosion of 5 kilotons of TNT.


  • Efficiency
  • The efficiency of a fission weapon performance and deployment is improved by reducing the fuel mass required for criticality. Particularly important in the Uranium bomb is the degree of enrichment of the fuel. Because of the impracticality of providing pure Uranium-235, the unavoidable presence of the unwanted Uranium-238 isoptope in the fuel requires that a greater mass of Uranium-235 is needed to compensate for neutron absorption by the Uranium-238. The Plutonium bomb does not suffer from this problem of dilution of the effective mass.

    Further ways of reducing the critical mass are outlined in the section on critical mass above.

    If the initial supercritical mass is only slightly higher than the critical mass, then the initial fissions from the chain reaction may reduce the density of the remaining fissile fuel thus reducing the fuel load to below the critical mass. In this case, the chain reaction will die out leaving the bomb damaged by the initial fissions and unable to detonate. This was called a "fizzle".


Nuclear Fusion

The Holy Grail of nuclear energy, nuclear fusion is the process by which the Sun generates its prodigious energy providing us with the warmth and light we receive. It is the process by which the nuclei two light atoms combine to form a single, bigger nucleus of a new atom releasing large amounts of energy as a consequence. In 1939 Hans Bethe explained that this process occurs in the stars all over the universe but up to now we have not been able to successfully duplicate this process on earth despite over 70 years of trying, but at last we are coming close.


The great attractions of nuclear fusion as an energy source are that the fuel, mostly isotopes of hydrogen, is plentiful and easy to obtain, and the elements produced as a result of the fusion are usually light and stable atoms rather than the heavy radioactive products which result from nuclear fission. Furthermore, the potential release of energy per unit mass of the fuel is much higher in the case of fusion than in fission since reactions allowing greater increases in binding energy are possible with fusion reactions. See the graph of binding energy above.


  • The Coulomb Barrier
  • Unfortunately, although bringing about fusion is theoretically possible, achieving it in practice is fraught with major difficulties.

    For fusion between two positively charged nuclei to take place, they must get close enough to eachother to undergo a nuclear reaction. For this to occur the nuclei must overcome the energy barrier due to the "repulsive" electrostatic Coulomb force, known as the Coulomb barrier, between the nuclei, to force them close enough to each other to come within the influence of, and be captured by, the "attractive" Strong nuclear force which holds the nucleons in each nucleus together.

    Coulomb Barrier

    The magnitude of the Coulomb barrier corresponds to the work done or energy needed for the two nuclei overcome the Coulomb force to come together. This is equal to the potential energy between the particles and is given by the Coulomb force between two nuclei multiplied by the distance between them integrated over the distance over which the force is effective. Thus for fusion to occur, the nuclei must have at least enough kinetic energy to exceed the Coulomb repulsion and this is proportional to the mass of the nuclei and the square of their velocity. The magnitude of the this kinetic energy is also directly proportional to the temperature of the nuclei.


    All fusion reactions require the fusing nuclei to have extremely high kinetic energies in order to overcome the Coulomb barrier and get close enough to each other to fuse. Their temperature must therefore be extremely high, 100 Million°C or more, so that the nuclei collide with eachother at great speed.


    • A Note About Temperatures:
    • The temperature and energy of a moving gas or plasma particle are directly proportional to its velocity squared.

      In nuclear physics, temperature is typically used to express the "average" energy of the particles in a fuel sample. Conversely, it is also common to express very high temperatures in terms of energy units (Joules or electronVolts).

      The energy in Joules is given by multiplying the temperature in degrees Kelvin by Boltzmann's constant of 1.38 X 10-23 Joules/degree Kelvin (J/K)

      Thus:

      1 Joule (J) ≡ 6.24 x 1012 Million electronVolts (MeV)

      and

      1000 electronVolts (KeV) ≡1.16 X 107 °K

      Fusion temperatures are so high that °Kelvin and °Celsius are almost the same and are often used interchangeably


      As a point of reference, the temperature at the core of the Sun is around 1.5 X 107 °K. This does not mean that all the atomic particles are at that temperature. This temperature represents the average energy of the atomic particles in the core. In thermal equilibrium, the atoms have a range of velocities (energies) described by the Maxwell-Boltzmann distribution which represents the number of particles at each energy level in the sample.


Maxwell-Boltzmann Temperature Distribution

The energy distribution shows a very high percentage of particles with energy levels around the average level and relatively low percentage of very low and very high energy particles at the lower and upper tails of the distribution. In absolute terms however, because of the extremely high particle density at the centre of the Sun, there will be a very large number of particles in the longer, upper tail with energies or temperatures many times higher than the mean


    The Coulomb barrier between two protons in free space is 3.43 MeV and this corresponds to a temperature of 4 × 1010 °K. This is over 1000 times the temperature of 1.3 KeV (1.5 X 107 °K) at the core of the Sun. How then can proton fusion occur on the Sun with such low particle energy levels? There are two explanations for this apparent anomaly.


    • The calculation of the Coulomb barrier determines the "average" energy per proton needed for fusion, however these energies are distributed according to the bell shaped Maxwell-Boltzmann distribution. Within its long tail there is a sufficiently large number of particles whose energy is much larger than the average and thus enough to initiate fusion.

    • It is not necessary for the incident protons to have sufficient energy to overcome the Coulomb barrier entirely. Due to the wave-particle duality and the statistical probabilities of the properties of very small particles, as explained by quantum mechanics, the protons can also pass through the barrier by a phenomenon known as quantum tunnelling, provided the barrier height is not too high above the kinetic energy of the incoming particle.

    Fuel Density

    For significant fusion to take place, the particle density of the fuel must also be very high to provide sufficient opportunities for collisions between the particles to occur.


    In a star, the high temperatures are provided by the self sustaining nature of the nuclear reaction itself and the density of the fuel is maintained by the star's massive gravity. On earth, attempts have been made to create these extreme conditions in a plasma of ionised gases but containment is a serious problem since no known materials for containing the fuels can withstand such high temperatures. An alternative is to capture the energy from a series of tiny, controlled thermonuclear explosions which has so far been more successful. See Nuclear Fusion - The Practice


    The story so far

    • Fusion Fuels
    • Fusing two light nuclei can liberate more than the fission of Uranium-235 or Plutonium-239. Ideal fuels are the lightest elements since they experience the lowest repulsive force, or Coulomb barrier, between their nuclei, so that the energy needed to bring about fusion is reduced. The most common fuels used in fusion attempts are Deuterium and Tritium, gaseous isotopes of hydrogen, in the so called D-T reaction.

      • Deuterium
      • Deuterium (2H) also known as heavy Hydrogen is a naturally occurring, stable isotope of Hydrogen found in the earth's oceans where it accounts for approximately 0.015% of the Hydrogen atoms, or 0.030% of the weight of Hydrogen. Deuterium is extracted from the water by a variety of separation methods which exploit the small differences in physical and chemical properties between Deuterium and Hydrogen.

        The Deuterium in one gallon of sea water has the energy content of 300 gallons of gasoline and the oceans contain enough energy to supply the world's energy needs for thousands of years..

      • Tritium
      • Tritium (3H) is also an isotope of Hydrogen. It is radioactive with a half-life of 12.3 years decaying at the rate of 5.5% per year by beta decay into Helium-3 with the release of an electron and of 18.6  keV of energy. Because of its short half-life, only tiny quantities are found naturally as the result of the reactions of cosmic rays with atmospheric gases. Supplies of Tritium are produced as a by-product of other nuclear reactions, notably those involving Lithium and much of it is reserved for nuclear weapons. It is consequently both rare and very expensive.

        Due to their low energy, the emitted electrons can not penetrate the skin and so Tritium is not considered an external radiation hazard though it could cause damage if inhaled or ingested. Tritium is however often used as a biological tracer in medical research because of its short half-life and low radiation.

      The fusion of Hydrogen nuclei (protons) in a proton-proton reaction is not practical since it would require too much energy or too high a temperature to start. The fusion of Deuterium with Tritium needs a temperature of 100 million to 150 million degrees Centigrade. All other fusion reactions need even higher temperatures.


    • Fusion Energy Release
    • The D-T fusion reaction between Deuterium and Tritium is shown below:


      Nuclear Fusion


      2H1    +    3H1    ⇒    4He2    +   1n0    +    @ 17.6 MeV


    The diagram above shows that the fusion of one atom of Deuterium with one atom of Tritium to form one atom of Helium (also called an alpha particle) releases about 17.6 MeV of energy.


    Note that this reaction results in the release of a troublesome surplus neutron which can cause problems in practical fusion reactors, such as the Tokamak. Since they carry no electric charge, neutrons are not constrained in the plasma by the magnetic field and can migrate to the walls of the reactor where they can react with parts of the reactor construction materials which may consequently become radioactive.

    This unavoidable side effect can however be turned to an advantage. By using a Lithium metal blanket to capture the surplus neutrons in the reactor, two useful fission reactions are possible, both of which result in the release of alpha particles (Helium nuclei) and, more importantly, the production of Tritium, the scarce, radioactive, isotope of Hydrogen, which is one of the basic fuels for the fusion reaction.

    The first reaction is exothermic and uses the isotope Lithium-6 to capture slow neutrons producing Tritium while releasing an alpha particle and 4.8 MeV of energy as follows:

     

    6Li3 + 1n04He2 + 3T1+ @ 4.8 MeV


    The second reaction is endothermic using the isotope Lithium-7 to capture fast neutrons, also producing Tritium and releasing an alpha particle while leaving a free neutron and absorbing 2.5 MeV of energy.


    7Li3 + 1n04He2 + 3T1+1n0 - @ 2.5 MeV


    Natural Lithium is relatively abundant in the earth's crust and is typically composed of 92.6% of the isotope Lithium-7 and 6.4% of Lithium-6.


    The energy released at the atomic level by the fusion of Deuterium and Tritium can be calculated from the binding energies of the parent and daughter atoms as shown in the following table:


    Corner

    Binding Energy Change with Fusion

    Corner

    Atom

    Number of Nucleons

    Binding Energy

    Per Nucleon (MeV)

    Total Binding Energy per Nuclide (MeV)

    Combined Binding Energy (MeV)

    Fission Energy Release (MeV)

    Deuterium-2

    2

    1.11

    2.22

    10.7

    3.5

    Tritium-3

    3

    2.83

    8.48

    Helium-4

    4

    7.1

    28.3

    28.3

    Neutron

    1

    0

    0

    0

    14.1


    The table shows that the combined binding energy of the Deuterium and Tritium atoms of 10.7 MeV increases to 28.3 MeV when the atoms fuse into Helium releasing energy of 17.6 MeV, equivalent to 2.8 X 10-12 Joules.

    Note that 80% of the released energy is carried by the neutron with the Helium alpha particle accounting for only 20%


    The energy released from practical amounts of fuel can be calculated as follows:


    The atomic mass of the Deuterium nuclide is 2 amu = 3.34 X 10-27Kg

    1 Kg of Deuterium therefore contains 1Kg/2 amu = 2.99 X 1026 atoms.

    The atomic mass of the Tritium nuclide is 3 amu and hence 1.5 Kg of Tritium also contains 2.99 X 1026 atoms.


    The energy released by fusion of 1 atom of Deuterium with 1 atom of Tritium is 17.6 Mev = 2.82 X 10-12 Joules.

    The energy liberated by the fusion of 1 Kg of Deuterium with 1.5 Kg of Tritium is therefore 2.82 X 10-12 X 2.99 X 1026 = 8.43 X 1014 Joules = (8.43 X 1014) / (3.6 X 1012) GWHours = 234 GWHours.

    This energy appears in the form of heat. If it was used to generate electricity in a conventional steam turbine power plant with an efficiency of 38%, it would provide 88,900 MWH of electricity which is near enough equivalent to one year's operation with a constant output power of 10 MWatts.


    Fission - Fusion Energy Comparison

    Note that the 234 GWH (8.43 X 1014 Joules) released by the fusion of 2.5 Kg of the fuel in the D-T (40-60 proportion) reaction above is equivalent to 93.6 GWH (3.37 X 1014 Joules) per Kg. This is over four times the 22.5 GWHours (8.1 X 1013 Joules) of energy released by the fission of 1 Kg of Uranium - 235 (see fission energy release above). The fusion reaction also uses safer fuels which are inexpensive, more plentiful, and easier to manage, leaving behind much more benign waste products resulting from the process.

    To put these values into perspective, 1 Kg of petrol (gasoline) has an energy content of about 4.7 X 107 Joules or (4.7 X 107) / (3.6 X 106) kWH = 13 kWH, less than one millionth of the energy from either nuclear fission or fusion. See also Energy Content Comparison Table


    Other Fusion Fuels

    There are actually four possible fusion reactions which could take place in a reactor fuelled by Deuterium only.


    2H1    +      2H1    ⇒    3He2    +   1n0     +    @ 3.3 MeV

    2H1    +      2H1    ⇒    3H1      +    1H1    +    @ 4.0 MeV

       2H1    +      3H1    ⇒    4He2    +    1n0    +    @ 17.6 MeV

       2H1    +     3He2   ⇒    4He2    +   1H1    +    @ 18.3 MeV

     

    The results of these four reactions can be summarised as follows:


        62H1   ⇒    21H1   +   24He2   +   21n0    +    @ 43.2 MeV

     

    The first two of the above reactions using only Deuterium as the fuel, known as D-D reactions are equally probable. This fuel combination has the advantage that the Deuterium fuel does not have the mildly radioactive properties of Tritium, but the energy release is relatively low.

    • The first reaction produces the He3 isotope of Helium and an energetic neutron.
    • The second reaction produces Hydrogen and Tritium which is mildly radioactive.

    The third and fourth reactions involve the Deuterium fuel reacting with the fusion products of the first two reactions producing a much higher energy release.

    • The third reaction is the well known D-T reaction between Deuterium and Tritium which produces a Helium atom (alpha particle) and a high energy neutron.
    • The fourth reaction between Deuterium and the Helium isotope He3 produces a Helium nucleus (alpha particle) and 2 energetic neutrons and is known as the D-He3 reaction.
    •  

    Other promising fusion fuel candidates are the Hydrogen-1 (proton) with / Boron reaction, which releases Helium (alpha particles).


    Solar Fusion

    Solar Fusion Chain

    Fusion in the Sun and Stars

    Solar fusion, which keeps the Sun and stars shining, is a multi-stage process initiated by the fusion of two Hydrogen nuclei (protons) in the following reaction in which the two protons fuse to form a Deuterium atom as one proton is transformed into a neutron, by the "weak nuclear reaction", with the release of a positron and a neutrino and 0.42 MeV of energy. See diagram opposite.


    1H1  +   1H1  ⇒    2H1   +    e+   +    ν   @ 0.42 MeV


    At the same time, the positron emitted by the beta decay of the proton is almost immediately annihilated with an electron, and their combined mass energy, as well as their kinetic energy, is carried off by two gamma ray photons.


    e+    +    e-    ⇒    2 γ   @1.02 MeV


    Proton - Proton (p-p) Chain Reaction

    After the initial reaction, solar fusion continues with more protons reacting with the Deuterium produced in the first reaction to form a light isotope of Helium releasing more energy in the following reaction and initiating a chain of reactions.


    2H1   +    1H1    ⇒    3He2    +    ν    @ 5.49 MeV

     

    In turn, the products of this second reaction fuse with even more particles to form ever more complex, heavier nuclei such as the Helium isotope 4He2 releasing two protons and more energy in further reactions such as the Deuterium D - D reactions above.

     

    Power from Nuclear Fusion

    Unfortunately immense amounts of energy are needed to create the conditions for self-sustaining fusion to take place and in practice there are serious technical problems to overcome in order to achieve a net energy gain. These are considered in the section on Nuclear Energy - The Practice


Physiological Effects of Nuclear Radiation

The term Nuclear Radiation normally refers to radiation with sufficient energy to cause ionisation of the materials on which it impinges.


  • The Cause
  • High-energy alpha (α), beta (β) and gamma (γ) radiation can transfer their energy upon interaction with other matter, knocking out electrons from neutral atoms or molecules on which they may impinge, leaving electron-deficient atoms or molecules called "positive ions" and free electrons in a process known as ionisation. This ionisation can be measured by counting the number of ions formed using devices such as Geiger counters.

    Alpha and beta rays are relatively harmless unless emitted inside the human body, but gamma rays cause damage similar to, but more serious than, X rays such as burns and cancerous mutations.

    Very high levels of radiation may not just strip electrons from their atoms, if high enough, it can cause disintegration of the atomic nucleus creating radioactive isotopes or in extreme cases causing the nucleus to split into smaller particles (nuclear disintegration or fission).

    Neutron radiation can induce non-radioactive atoms, including the body tissues, to become radioactive, which makes it one of the most dangerous radiations. This capability however also has practical applications in manufacturing isotopes for use in nuclear medicine.


    See more about RF radiation damage and X-rays.


  • The Exposure
  • The exposure to ionising radiation is measured in terms of the amount of energy imparted by the radiation to the material through which it is passing and is known as the radiation dose, expressed in "Gray" (Gy) after the British medical physicist. One Gray corresponds to the deposition of 1 Joule of energy in 1 kg of the exposed material.


  • The Effect
  • When nuclear radiation strikes complex biological molecules, such as proteins or nucleic acids, it may fracture the molecules and prevent their proper functioning. This can result in rupturing the cell membranes, loss of cell vitality, decreased enzyme activity, initiation of cancer, and genetic mutations. Rupturing of the cells causes them to lose their contents and die and ultimately the functions associated with the cells cease. Death occurs because of the direct loss of vital organs or because of secondary infections resulting from the breakdown of the immune system. The effects are cumulative and depend on the type of radiation and the dose received.


    The magnitude of the effect depends on the intensity of the radiation, the distance from the source, the presence of absorbent materials in the intervening space (including air) and the duration of the exposure. Radiation workers wear badges made of photographic film which indicate the exposure to radiation.


    The actual biological damage caused by the radiation depends on its physiological effect and is measured in Sieverts (Sv) after the Swedish medical physicist. Sieverts are related to Gray by a so called "quality factor" (Q) representing their potential for doing damage. A more appropriate name for the weighting factor would perhaps have been the "damage factor".

    The Gray is the dose, the Sievert is the corresponding biological risk.

    • 1 Joule of beta or gamma radiation absorbed per Kg of tissue (1 Gy) has 1 Sievert (Sv) of biological effect. (Q=1)
    • 1 J/Kg (1 Gy) of alpha radiation has 20 Sv effect (Q=20)
    • 1 J/Kg (1 Gy) of neutrons has a 10 Sv effect (Q=10)

  • Radiation Dose Safety Limit
  • The Sievert is a relatively large unit with an exposure of 1 Sievert increasing the risk of cancer by 5%, while an exposure of 10 Sieverts can be fatal within days. Typical exposure levels are much lower and are measured in millisieverts (mSv).

    The average exposure in the United States, from natural sources of radiation, mostly cosmic radiation and radon gas released from the earth's crust, is 3 mSv (300 millirems) per year at sea level and slightly higher at higher elevations. Similarly the average yearly background radiation in the UK is 2 mSv.

    The current federal occupational limit of exposure per year for an adult worker "as low as reasonably achievable (ALARA); however, not to exceed 20 mSv (2,000 millirems)above the 3 mSv of natural sources of radiation and any medical radiation. For workers using radiation the limit is slightly higher at 50 mSV above background . Readings typically are taken monthly. A federal advisory committee recommends that the lifetime exposure be limited to a person's age multiplied by 10 mSv (example: for a 65-year-old person, 650 mSv).


  • Radiation Dose from Medical Radiological Tests
  • Typical exposures from medical investigations using X-rays are as follows:

    • Single chest X-ray                 0.1 mSv
    • Single mammogram             3 mSv
    • Full body CAT or CT scan   10 mSv

See also Physiological Effects of Electromagnetic Radiation


See also Radioisotope Thermoelectric Generators (RTG) - The Nuclear Battery


See Nuclear Energy - The Practice for electricity generation by nuclear fission and nuclear fusion.


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